Class 9 Science – Chapter 3: Atoms and Molecules (Detailed Notes)

Class 9 Science – Chapter 3: Atoms and Molecules (Detailed Notes)

1. Laws of Chemical Combination

(a) Law of Conservation of Mass

  • Mass can neither be created nor destroyed in a chemical reaction.
  • Total mass of reactants = Total mass of products.

(b) Law of Constant Proportions

  • A pure compound always contains the same elements in a fixed proportion by mass.
  • Example: Water (H2O) always contains hydrogen and oxygen in the ratio 2:16 (or 1:8).

2. Dalton’s Atomic Theory

  • All matter is made of tiny particles called atoms.
  • Atoms are indivisible and indestructible.
  • Atoms of a given element are identical in mass and properties.
  • Atoms combine in simple whole-number ratios to form compounds.
  • In a chemical reaction, atoms are rearranged but not destroyed.

3. What is an Atom?

  • An atom is the smallest particle of an element which may or may not have an independent existence.
  • Examples: H, O, N, etc.

Symbols of Elements (as given by Dalton and IUPAC)

  • Each element is represented by a symbol (usually first one or two letters of English or Latin name).
  • Examples: Hydrogen – H, Carbon – C, Sodium – Na, Potassium – K, etc.

4. Atomic Mass

  • Atomic mass is the mass of an atom compared to 1/12th the mass of one atom of carbon-12 isotope.
  • It is a relative quantity and has no unit.
  • Example: H = 1, C = 12, O = 16, Na = 23, Cl = 35.5, etc.

5. Molecule

  • A molecule is a group of two or more atoms chemically bonded together.
  • Can be atoms of same element or different elements.

Types of Molecules:

  • Monoatomic: He, Ne, Ar (noble gases)
  • Diatomic: H2, O2, Cl2, N2
  • Polyatomic: O3, P4, S8

Molecules of Compounds:

  • Formed by atoms of different elements.
  • Examples: Water (H2O), Ammonia (NH3), Carbon dioxide (CO2).

6. Ions

  • Charged particles formed by loss or gain of electrons.

Types:

  • Cation (+): Loss of electron(s) (e.g., Na+, Ca2+)
  • Anion (–): Gain of electron(s) (e.g., Cl–, O2–)

Radicals:

  • Groups of atoms that carry charge and behave as a single ion (e.g., OH–, SO42–)

7. Chemical Formulae

  • A symbolic representation of a molecule using symbols and subscripts.
  • Example: H2O, CO2, NaCl, Ca(OH)2, etc.

Rules for Writing Chemical Formulae:

  1. Write the symbols of elements or ions.
  2. Write valency of each element.
  3. Cross multiply the valencies.
  4. Simplify the ratio if needed.

Examples:

  • Sodium chloride: Na+ Cl– → NaCl
  • Magnesium chloride: Mg2+ Cl– → MgCl2
  • Aluminium oxide: Al3+ O2– → Al2O3

8. Molecular Mass

  • Sum of atomic masses of all atoms in a molecule.
  • Example: H2O = 2×1 + 1×16 = 18 u

9. Formula Unit Mass

  • Used for ionic compounds. It is the sum of atomic masses of all atoms in a formula unit of an ionic compound.

10. Mole Concept

  • 1 mole = 6.022 × 1023 particles (Avogadro's number)
  • Molar mass: Mass of 1 mole of a substance in grams.
  • Moles = Given mass / Molar mass

Examples:

  • 1 mole of H2O = 6.022 × 1023 molecules of water = 18 g
  • 1 mole of Na = 6.022 × 1023 atoms of sodium = 23 g

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